OSAKA UNIV. CBCMP

OSAKA UNIVERSITY CHEMISTRY - BIOLOGY COMBINED MAJOR PROGRAM

Physical Chemistry 3

Outline

Physical Chemistry 3 will deal with reaction kinetics and reactor design for homogeneous reactions. Students will learn about rates of reaction, stoichiometry and order, different types of reactions, and the effect of temperature on reaction rates as well corresponding reaction mechanisms. Practical applications on reactor design based on reaction kinetics would also be discussed.

Learning outcomes

At the end of this course, students should be able to:

  • Discuss concepts in reaction kinetics qualitatively
  • Derive and solve rate equations specific to chemical reactions
  • Carry out calculations for reactions with several mechanism steps
  • Choose and use appropriate methods to determine reaction rates from experimental data
  • Determine which reactor would be best suited for a specific reaction based on their kinetics

Textbook

References:

Chemical Reaction Engineering, 3rd Edition

O. Levenspiel

ISBN: 9780471254249

 

Physical Chemistry, 10th Edition

P. W. Atkins and J. D. Paula

ISBN: 9780199697403

 

Physical Chemistry: A Molecular Approach

D. A. McQuarrie and J. D. Simon

ISBN: 9780935702996

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Syllabus

Molecules in Motion

Transport in gases

Motion in liquids

Diffusion

Reaction Dynamics

Collision theory

Chemical Kinetics: Rate Laws

Definition of rate law

Rate constant and its temperature dependence

Rate laws for constant volume reactions

Varying-volume batch reactions

Experimental determination of rate laws

Chemical Kinetics: Reaction Mechanism

Elementary reactions

Principle of detailed balanced states

Complex reactions

Rate-determining step

Steady-state approximation

Kinetic control of reactions

Introduction to Reactor Design

Material and energy balance

Relationship between concentration and conversion

Ideal reactors for a single reaction

Graphical representation of ideal reactors

Design for Single Reactions

Size comparison of single reactors

Multiple-reactor systems

Recycle reactor and autocatalytic reactions

Design for Multiple Reactions

Parallel reactions

Series reactions

Irreversible series-parallel reactions

Temperature and Pressure Effects

Heats of reaction

Equilibrium constants

Graphical design

Optimum temperature progression

Multiple reactions

Choosing the Right Reactor

 

This syllabus is meant to be a guide and was made to provide an overview for the course. However, circumstances may require some changes to be made during the span of the semester. In such case, students will be notified if there will be any changes made to the syllabus.

Grading

 

For the Lecture Class:

     Exams                     90%

     Attendance            10%

 

For the Exercise Class:

     Short Quizzes        30%

     Exercises                60%

     Attendance            10%

Instructor

Assistant Professor

Christian David Cruz Pangilinan

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